Construction of efficient photoanodes for dye sensitized solar cells: TiO2 films with a gradient content of graphene

Abstract

Graphene has attracted a lot of attention because of its unique optical, thermal, mechanical and electrical properties. In this study, the effect of graphene on the performance of dye sensitized solar cells (DSSCs) was investigated by constructing TiO₂ photoanodes with a gradient graphene content. After the construction of photoanodes with a gradient graphene content, the DSSCs displayed a higher dye loading amount, lower internal resistances, lower electron recombination rate and faster electron transport rate, which resulted in high open circuit voltage and current density. Under the optimum conditions, the DSSC exhibited a V_oc of 0.72 V, a J_sc of 17.11 mA cm⁻², a FF of 0.63, and an energy conversion efficiency (η) of 7.71%, indicating a 41% increase in η than that of the DSSC based on a pure TiO₂ photoanode, which gives a V_oc of 0.69 V, a J_sc of 12.63 mA cm⁻², a FF of 0.62, and an η value of 5.45%. The construction of TiO₂ photoanodes with a gradient graphene content could really enhance the efficiency of DSSCs by improving the dye loading amount and enhancing the electron bridge effect of graphene from TiO₂ to the FTO, which lowered the electron recombination rate and accelerated the electron transport rate.