The influence of charge on the performance of monocationic and dicationic triazol(ium)-based halogen bond donors was investigated. Next to the activity in a halide abstraction benchmark reaction, halogen bonding was also evaluated via X-ray structural analyses and isothermal titration calorimetry.
A. Dreger, E. Engelage, B. Mallick, P. D. Beer and S. M. Huber, Chem. Commun., 2018, 54, 4013 DOI: 10.1039/C8CC00527C
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