Photophysical characterization of a highly luminescent divalent-europium-containing azacryptate†
Tyler C.
Jenks, 
a
Matthew D.
Bailey,
a
Brooke A.
Corbin,
a
Akhila N. W.
Kuda-Wedagedara,
a
H. Bernhard
Schlegel,
*a
Federico A.
Rabuffetti
*a
and
Matthew J.
Allen
*a
a
Matthew D.
Bailey,
a
Brooke A.
Corbin,
a
Akhila N. W.
Kuda-Wedagedara,
a
H. Bernhard
Schlegel,
*a
Federico A.
Rabuffetti
*a
and
Matthew J.
Allen
*a
Abstract
We report a new luminescent EuII-containing complex. The complex is excited with visible light, leading to emission centered at 447 nm with a lifetime of 1.25 μs. Computational studies suggest that the steric bulk of the ligand is a major factor influencing the wavelength of emission.
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