Issue 33, 2018
From the journal:

Chemical Communications

Rectangle and [2]catenane from cluster modular construction†

Xiao-Ting Qiu,ab   Rui Yao,a   Wen-Fa Zhou,c   Meng-Di Liu,a   Quan Liu,a   Ying-Lin Song,c   David J. Young, ORCID logo d   Wen-Hua Zhang ORCID logo *a  and  Jian-Ping Lang ORCID logo *ab  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, Jiangsu, P. R. China
E-mail: jplang@suda.edu.cn, whzhang@suda.edu.cn
Fax: +86-512-65880328

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

c School of Physical Science and Technology, Soochow University, Suzhou 215006, Jiangsu, P. R. China

d Faculty of Science, Health, Education and Engineering, University of the Sunshine Coast, Maroochydore DC, Queensland, Australia

Abstract

Reaction of [Et4N][Tp*WS3] (1) with [Cu(MeCN)4]PF6, CsCl, isonicotinic acid and CuCN, and treatment of [Et4N][Tp*WS3(CuCl)3] (2)/[Et4N][{Tp*WS3Cu3Cl}2(μ-Cl)2(μ4-Cl)] (3) with AgOTf and bpp (Tp* = hydridotris(3,5-dimethylpyrazol-1-yl)borate; bpp = 1,3-di(4-pyridyl)propane) give rise to [Et4N]2[{Tp*WS3Cu3(CN)0.5}2(μ-Cl)2(μ4-Cl)]2(PF6)2 (4) and [(Tp*WS3Cu3)2(μ3-Cl)2(bpp)3]2(OTf)4 (5), respectively. Compounds 4 and 5 feature cluster-based rectangle and [2]catenane architecture, and both exhibit enhanced third-order nonlinear optical responses relative to those of 1.

Graphical abstract: Rectangle and [2]catenane from cluster modular construction

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8CC01950A
Article type
Communication
Submitted
11 Mar 2018
Accepted
29 Mar 2018
First published
03 Apr 2018

Chem. Commun., 2018,54, 4168-4171

Permissions

Request permissions

Rectangle and [2]catenane from cluster modular construction

X. Qiu, R. Yao, W. Zhou, M. Liu, Q. Liu, Y. Song, D. J. Young, W. Zhang and J. Lang, Chem. Commun., 2018, 54, 4168 DOI: 10.1039/C8CC01950A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements