Carbodiimides as catalysts for the reduction of CO2 with boranes

Alberto Ramos; Antonio Antiñolo; Fernando Carrillo-Hermosilla; Rafael Fernández-Galán; Antonio Rodríguez-Diéguez; Daniel García-Vivó

doi:10.1039/C8CC02139B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Carbodiimides as catalysts for the reduction of CO₂ with boranes†

Alberto Ramos,

*^a Antonio Antiñolo,

*^a Fernando Carrillo-Hermosilla,

^a Rafael Fernández-Galán,

^a Antonio Rodríguez-Diéguez

^b and Daniel García-Vivó

Author affiliations

* Corresponding authors

^a Departamento de Química Inorgánica, Orgánica y Bioquímica, Facultad de Ciencias y Tecnologías Químicas, Universidad de Castilla-La Mancha, Campus Universitario, E-13071 Ciudad Real, Spain
E-mail: Alberto.Ramos@uclm.es, Antonio.Antinolo@uclm.es

^b Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Avenida de la Fuente Nueva S/N, 18071 Granada, Spain

^c Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain

Abstract

Carbodiimides catalyse the reduction of CO₂ with H-BBN or BH₃·SMe₂ to give either mixtures of CH₂(OBBN)₂ and CH₃OBBN or (MeOBO)₃ and B(OMe)₃ under mild conditions (25–60 °C, 1 atm CO₂). Stoichiometric reactions and theoretical calculations were performed to unveil the mechanism of these catalytic processes.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C8CC02139B
Article type: Communication
Submitted: 16 Mar 2018
Accepted: 13 Apr 2018
First published: 13 Apr 2018

Download Citation

Chem. Commun., 2018,54, 4700-4703

Permissions

Request permissions

Carbodiimides as catalysts for the reduction of CO₂ with boranes

A. Ramos, A. Antiñolo, F. Carrillo-Hermosilla, R. Fernández-Galán, A. Rodríguez-Diéguez and D. García-Vivó, Chem. Commun., 2018, 54, 4700 DOI: 10.1039/C8CC02139B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications