Issue 45, 2018
From the journal:

Chemical Communications

A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes†

Fan Zhang,‡a   Xiao-Ming Cao, ORCID logo ‡b   Jiwei Wang,a   Jiajun Jiao,a   Yongming Huang,*a   Min Shi,ac   Pierre Braunstein ORCID logo d  and  Jun Zhang ORCID logo *a  

* Corresponding authors

a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Mei Long Road, Shanghai 200237, China
E-mail: zhangj@ecust.edu.cn, huangym@ecust.edu.cn

b Center for Computational Chemistry and Research Institute of Industrial Catalysis, School of Chemistry & Molecular Engineering, East China University of Science and Technology, 130 Mei Long Road, Shanghai 200237, China

c State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China

d Université de Strasbourg, CNRS, CHIMIE UMR 7177, Laboratoire de Chimie de Coordination, 4 rue Blaise Pascal, 67081 Strasbourg Cedex, France

Abstract

Homo (Au3)- and heterotrinuclear coinage metal complexes (Au2Ag and Au2Cu) ligated by the first tritopic carbanionic N-heterocyclic carbene (NHC) have been prepared by deprotonation of ditopic NHC digold complexes and structurally characterized by single-crystal X-ray diffraction.

Graphical abstract: A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes

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Article information

DOI
https://doi.org/10.1039/C8CC02192A
Article type
Communication
Submitted
19 Mar 2018
Accepted
06 May 2018
First published
09 May 2018

Chem. Commun., 2018,54, 5736-5739

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A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes

F. Zhang, X. Cao, J. Wang, J. Jiao, Y. Huang, M. Shi, P. Braunstein and J. Zhang, Chem. Commun., 2018, 54, 5736 DOI: 10.1039/C8CC02192A

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