The sterically accessible carbide complex, (Cy3P)Cl3Ru![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
C–PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.
A. Reinholdt, A. F. Hill and J. Bendix, Chem. Commun., 2018, 54, 5708 DOI: 10.1039/C8CC03596B
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