Issue 72, 2018

The self-assembly and metal adatom coordination of a linear bis-tetrazole ligand on Ag(111)

Abstract

We employ a linear linker molecule consisting of a benzene functionalised with two tetrazole moieties at para positions. Its self-assembly and coordination with the native silver adatoms and codeposited Fe adatoms on a Ag(111) surface under ultra high vacuum conditions are investigated by means of scanning tunnelling microscopy and X-ray photoelectron spectroscopy. We discover a rich spectrum of room-temperature stable Ag and Fe2+ coordination nodes depending on the formation temperature.

Graphical abstract: The self-assembly and metal adatom coordination of a linear bis-tetrazole ligand on Ag(111)

Supplementary files

Article information

Article type
Communication
Submitted
30 May 2018
Accepted
14 Aug 2018
First published
14 Aug 2018

Chem. Commun., 2018,54, 10072-10075

The self-assembly and metal adatom coordination of a linear bis-tetrazole ligand on Ag(111)

P. Knecht, N. Suryadevara, B. Zhang, J. Reichert, M. Ruben, J. V. Barth, S. Klyatskaya and A. C. Papageorgiou, Chem. Commun., 2018, 54, 10072 DOI: 10.1039/C8CC04323J

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