Issue 66, 2018
From the journal:

Chemical Communications

Dihydrogen phosphate-containing dinuclear double assemblies that demonstrate phosphate reactivity to the tetrafluoroborate anion†

Robert A. Faulkner, ORCID logo a   Nathan J. Patmore, ORCID logo a   Craig R. Rice ORCID logo *a  and  Christopher Slatera  

* Corresponding authors

a Department of Chemical Sciences, School of Applied Sciences, University of Huddersfield, Huddersfield HD1 3DH, UK
E-mail: c.r.rice@hud.ac.uk

Abstract

The ligands L1 and L2 both form dinuclear assemblies with Cu(II) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly (e.g. [Cu2L2(H2PO4)]3+). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu3(L1)3(O3POBF3)]3+ and [Cu2(L2)2(O2P(OBF3)2)]+.

Graphical abstract: Dihydrogen phosphate-containing dinuclear double assemblies that demonstrate phosphate reactivity to the tetrafluoroborate anion

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Article information

DOI
https://doi.org/10.1039/C8CC04900A
Article type
Communication
Submitted
19 Jun 2018
Accepted
18 Jul 2018
First published
19 Jul 2018

Chem. Commun., 2018,54, 9159-9162

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Dihydrogen phosphate-containing dinuclear double assemblies that demonstrate phosphate reactivity to the tetrafluoroborate anion

R. A. Faulkner, N. J. Patmore, C. R. Rice and C. Slater, Chem. Commun., 2018, 54, 9159 DOI: 10.1039/C8CC04900A

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