Issue 73, 2018

Induced circular dichroism of monoatomic anions: silica-assisted the transfer of chiral environment from molecular assembled nanohelices to halide ions

Abstract

We demonstrate the first example of induced CD of monoatomic anions. This was detected using chirally-arranged molecular assemblies of non-chiral cationic gemini surfactants (16-2-16) with monoatomic anions stabilized with silica-coating. Furthermore, we have also achieved multi-step transfer of a chiral environment through an in situ chemical reaction via chiralized monoatomic anions.

Graphical abstract: Induced circular dichroism of monoatomic anions: silica-assisted the transfer of chiral environment from molecular assembled nanohelices to halide ions

Supplementary files

Article information

Article type
Communication
Submitted
06 Jul 2018
Accepted
01 Aug 2018
First published
01 Aug 2018

Chem. Commun., 2018,54, 10244-10247

Author version available

Induced circular dichroism of monoatomic anions: silica-assisted the transfer of chiral environment from molecular assembled nanohelices to halide ions

Y. Okazaki, N. Ryu, T. Buffeteau, S. Pathan, S. Nagaoka, E. Pouget, S. Nlate, H. Ihara and R. Oda, Chem. Commun., 2018, 54, 10244 DOI: 10.1039/C8CC05449E

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