Issue 81, 2018
From the journal:

Chemical Communications

Carboallylation of electron-deficient alkenes by palladium/copper catalysis†‡

Kazuhiko Semba, ORCID logo *a   Naoki Ohta,a   Yuko Yanoa  and  Yoshiaki Nakao ORCID logo *a  

* Corresponding authors

a Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: semba.kazuhiko.5n@kyoto-u.ac.jp, nakao.yoshiaki.8n@kyoto-u.ac.jp

Abstract

A method for the carboallylation of electron-deficient alkenes with tetraorganosilicon reagents and allylic carbonates based on Pd/Cu catalysis has been developed. This method affords a wide range of structurally diverse carbon skeletons from readily available starting materials, and tolerates various functional groups.

Graphical abstract: Carboallylation of electron-deficient alkenes by palladium/copper catalysis

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Article information

DOI
https://doi.org/10.1039/C8CC06023A
Article type
Communication
Submitted
25 Jul 2018
Accepted
16 Sep 2018
First published
17 Sep 2018

Chem. Commun., 2018,54, 11463-11466

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Carboallylation of electron-deficient alkenes by palladium/copper catalysis

K. Semba, N. Ohta, Y. Yano and Y. Nakao, Chem. Commun., 2018, 54, 11463 DOI: 10.1039/C8CC06023A

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