Photo-induced free radical production in a tetraphenylethylene ligand-based metal–organic framework

Kui Xu; Bing Yu; Yuanyuan Li; Huifang Su; Bingnan Wang; Kai Sun; Yuanyuan Liu; Qiuchen Peng; Hongwei Hou; Kai Li

doi:10.1039/C8CC06662K

Photo-induced free radical production in a tetraphenylethylene ligand-based metal–organic framework†

Kui Xu,‡^a Bing Yu,

‡^a Yuanyuan Li,

*^b Huifang Su,^c Bingnan Wang,^a Kai Sun,

^a Yuanyuan Liu,^a Qiuchen Peng,^ab Hongwei Hou

*^a and Kai Li

*^a

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* Corresponding authors

^a College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China
E-mail: likai@zzu.edu.cn

^b College of Chemistry, Chemical and Environmental Engineering, Henan University of Technology, Zhengzhou 450001, P. R. China

^c Department of Osteology, The First Affiliated Hospital of Zhengzhou University, Zhengzhou 450001, P. R. China

Abstract

Photo-induced free radical production was observed in tetraphenylethylene ligand-based metal–organic frameworks (MOFs). This feature endows the MOFs with reversible, fast, obvious, and controllable photo-induced color/emission transformation, excellent fatigue resistance ability and good light stability.

Chemical Communications

Photo-induced free radical production in a tetraphenylethylene ligand-based metal–organic framework†

Abstract

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Photo-induced free radical production in a tetraphenylethylene ligand-based metal–organic framework

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