Modification of amine-cured epoxy resins by boronic acids based on their reactivity with intrinsic diethanolamine units

Yumiko Ito; Jumpei Kida; Daisuke Aoki; Hideyuki Otsuka

doi:10.1039/C8CC07412G

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Modification of amine-cured epoxy resins by boronic acids based on their reactivity with intrinsic diethanolamine units†

Yumiko Ito,^a Jumpei Kida,^a Daisuke Aoki

^a and Hideyuki Otsuka

*^a

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* Corresponding authors

^a Department of Chemical Science and Engineering, Tokyo Institute of Technology, 2-12-1 S1-6 Ookayama, Meguro-ku, Tokyo 152-8550, Japan
E-mail: otsuka@polymer.titech.ac.jp

Abstract

Amine-cured epoxy polymers were modified after curing, exploiting the reactivity of their intrinsic diethanolamine (DEA) units toward boronic acids. The condensation of DEA units with various boronic acids resulted in changes in the thermal, mechanical, and optical properties of the original amine-cured epoxy polymers.

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DOI: https://doi.org/10.1039/C8CC07412G
Article type: Communication
Submitted: 12 Sep 2018
Accepted: 11 Oct 2018
First published: 11 Oct 2018

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Chem. Commun., 2018,54, 12930-12933

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Modification of amine-cured epoxy resins by boronic acids based on their reactivity with intrinsic diethanolamine units

Y. Ito, J. Kida, D. Aoki and H. Otsuka, Chem. Commun., 2018, 54, 12930 DOI: 10.1039/C8CC07412G

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Chemical Communications

Modification of amine-cured epoxy resins by boronic acids based on their reactivity with intrinsic diethanolamine units†

Abstract

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Modification of amine-cured epoxy resins by boronic acids based on their reactivity with intrinsic diethanolamine units

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