Issue 95, 2018
From the journal:

Chemical Communications

A homochiral Zn–Dy heterometallic left-handed helical chain complex without chiral ligands: anion-induced assembly and multifunctional integration†

Cai-Ming Liu, ORCID logo *a   De-Qing Zhang, ORCID logo *a   Ren-Gen Xiong,*b   Xiang Haoa  and  Dao-Ben Zhu ORCID logo a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: cmliu@iccas.ac.cn, dqzhang@iccas.ac.cn

b Ordered Matter Science Research Center, Southeast University, Nanjing 211189, China
E-mail: xiongrg@seu.edu.cn

Abstract

Both second-order nonlinear optical and single-molecule magnet properties are observed in a novel 1D homochiral Zn–Dy heterometallic left-handed helical chain complex (1) without chiral ligands, which evolves from a Zn3Dy2 pentanuclear cluster complex (2), thanks to the structural guiding role of perchlorate anions.

Graphical abstract: A homochiral Zn–Dy heterometallic left-handed helical chain complex without chiral ligands: anion-induced assembly and multifunctional integration

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Article information

DOI
https://doi.org/10.1039/C8CC07468B
Article type
Communication
Submitted
14 Sep 2018
Accepted
05 Nov 2018
First published
05 Nov 2018

Chem. Commun., 2018,54, 13379-13382

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A homochiral Zn–Dy heterometallic left-handed helical chain complex without chiral ligands: anion-induced assembly and multifunctional integration

C. Liu, D. Zhang, R. Xiong, X. Hao and D. Zhu, Chem. Commun., 2018, 54, 13379 DOI: 10.1039/C8CC07468B

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