Retracted Article: Insight into the reversible structural crystalline-state transformation from MIL-53(Al) to MIL-68(Al)

Adelaida Perea-Cachero; Enrique Romero; Carlos Téllez; Joaquín Coronas

doi:10.1039/C7CE02034A

Retracted Article: Insight into the reversible structural crystalline-state transformation from MIL-53(Al) to MIL-68(Al)†

Adelaida Perea-Cachero,

^a Enrique Romero,^b Carlos Téllez

*^a and Joaquín Coronas

^a

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* Corresponding authors

^a Chemical and Environmental Engineering Department, Instituto de Nanociencia de Aragón (INA), Universidad de Zaragoza, 50018 Zaragoza, Spain
E-mail: ctellez@unizar.es

^b Chemical and Environmental Engineering Department, Instituto de Investigación en Ingeniería de Aragón (I3A), Universidad de Zaragoza, 50018 Zaragoza, Spain

Abstract

The reversible crystalline transformation between MIL-53(Al) and MIL-68(Al) is described. This followed a uniform conversion model with cleavage and formation of metal–ligand bonds after exchange or removal of guest molecules. MIL-68(Al) materials produced during the transformations had higher thermal stability and crystallinity than the as-synthesized MIL-68(Al).

CrystEngComm

Retracted Article: Insight into the reversible structural crystalline-state transformation from MIL-53(Al) to MIL-68(Al)†

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