Distal radical migration strategy: an emerging synthetic means

Weipeng Li; Wentao Xu; Jin Xie; Shouyun Yu; Chengjian Zhu

doi:10.1039/C7CS00507E

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Distal radical migration strategy: an emerging synthetic means

Weipeng Li,^a Wentao Xu,^a Jin Xie,

*^a Shouyun Yu

*^a and Chengjian Zhu

*^ab

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, P. R. China
E-mail: xie@nju.edu.cn, yushouyun@nju.edu.cn, cjzhu@nju.edu.cn

^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 200032, P. R. China

Abstract

The remote radical migration strategy has gained considerable momentum. During the past three years, we have witnessed the rapid development of sustainable and practical C–C and C–H bond functionalization by means of long-distance 1,n-radical migration (n = 4, 5, 6) events. Its advent brings our chemical community a new platform to deal with the challenging migration transformations and thus complements the existing ionic-type migration protocols. In this review, the recent achievements in distal radical migration triggered C–C and C–H bond functionalization are summarized.

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DOI: https://doi.org/10.1039/C7CS00507E
Article type: Tutorial Review
Submitted: 24 Sep 2017
First published: 27 Nov 2017

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Chem. Soc. Rev., 2018,47, 654-667

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Distal radical migration strategy: an emerging synthetic means

W. Li, W. Xu, J. Xie, S. Yu and C. Zhu, Chem. Soc. Rev., 2018, 47, 654 DOI: 10.1039/C7CS00507E

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Distal radical migration strategy: an emerging synthetic means

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