Constructing CrIII-centered heterometallic complexes: [NiII6CrIII] and [CoII6CrIII] wheels

Foteini E. Kakaroni; Alexandra Collet; Eirini Sakellari; Demetrios I. Tzimopoulos; Milosz Siczek; Tadeusz Lis; Mark Murrie; Constantinos J. Milios

doi:10.1039/C7DT04043A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Constructing Cr^III-centered heterometallic complexes: [Ni ^II₆Cr^III] and [Co ^II₆Cr^III] wheels†

Foteini E. Kakaroni,^a Alexandra Collet,^b Eirini Sakellari,^a Demetrios I. Tzimopoulos,^c Milosz Siczek,^d Tadeusz Lis,^d Mark Murrie

*^b and Constantinos J. Milios

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Crete, Voutes 71003, Herakleion, Greece
E-mail: komil@uoc.gr

^b WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow, UK
E-mail: Mark.Murrie@glasgow.ac.uk

^c Department of Chemistry, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece

^d Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, Wroclaw 50-383, Poland

Abstract

The solvothermal reaction between Cr(acac)₃, MCl₂·6H₂O (M = Ni, Co) and 2-hydroxy-4-methyl-6-phenyl-pyridine-3-amidoxime (H₂L), under basic conditions, led to the synthesis of the heterometallic heptanuclear clusters [M^II₆Cr(HL_zw)₆(HL)₆]·3Cl (M = Ni, 1; Co, 2), with the nickel analogue displaying an S = 9/2 spin ground-state.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C7DT04043A
Article type: Communication
Submitted: 27 Oct 2017
Accepted: 17 Nov 2017
First published: 17 Nov 2017

Download Citation

Dalton Trans., 2018,47, 58-61

Permissions

Request permissions

Constructing Cr^III-centered heterometallic complexes: [Ni^II₆Cr^III] and [Co^II₆Cr^III] wheels

F. E. Kakaroni, A. Collet, E. Sakellari, D. I. Tzimopoulos, M. Siczek, T. Lis, M. Murrie and C. J. Milios, Dalton Trans., 2018, 47, 58 DOI: 10.1039/C7DT04043A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions