Issue 18, 2018
From the journal:

Dalton Transactions

Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate†

Jiage Jia,a   Pengtao Ma,a   Panpan Zhang,a   Dongdi Zhang, ORCID logo a   Chao Zhang, ORCID logo a   Jingyang Niu ORCID logo *a  and  Jingping Wang ORCID logo *a  

* Corresponding authors

a Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China
E-mail: jyniu@henu.edu.cn, jpwang@henu.edu.cn
Fax: +86 371-2388 6876

Abstract

A monomeric trinickel(II)-substituted phosphotungstate [H9P2W15O62Ni3]9− ion is stabilized by grafting three {Re(CO)3} organometallic groups on the surface for the first time. Magnetic measurements manifest that the resulting complex, Na(NH4)5[P2W15O56Ni3(H2O)3(μ3-OH)3(Re(CO)3)3]·18H2O (1), displays overall ferromagnetic interactions with the presence of ZFS for Ni2+ at low temperature.

Graphical abstract: Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate

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Article information

DOI
https://doi.org/10.1039/C8DT00138C
Article type
Communication
Submitted
11 Jan 2018
Accepted
02 Apr 2018
First published
02 Apr 2018

Dalton Trans., 2018,47, 6288-6292

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Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate

J. Jia, P. Ma, P. Zhang, D. Zhang, C. Zhang, J. Niu and J. Wang, Dalton Trans., 2018, 47, 6288 DOI: 10.1039/C8DT00138C

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