Evaluating the component contribution to nonlinear optical performances using stable [Ni4O4] cuboidal clusters as models

Zhi-Min Hao; Meng-Yao Chao; Yan Liu; Ying-Lin Song; Jun-Yi Yang; Lifeng Ding; Wen-Hua Zhang; Jian-Ping Lang

doi:10.1039/C8DT02080A

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Evaluating the component contribution to nonlinear optical performances using stable [Ni₄O₄] cuboidal clusters as models†

Zhi-Min Hao,^a Meng-Yao Chao,^a Yan Liu,^a Ying-Lin Song,^b Jun-Yi Yang,*^b Lifeng Ding,*^c Wen-Hua Zhang

*^a and Jian-Ping Lang

*^a

Author affiliations

* Corresponding authors

^a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
E-mail: whzhang@suda.edu.cn, jplang@suda.edu.cn

^b College of Physics, Optoelectronics, and Energy, Soochow University, Suzhou 215006, China
E-mail: yjy2010@suda.edu.cn

^c Department of Chemistry, Xi'an Jiaotong-Liverpool University, Suzhou 215123, China
E-mail: lifeng.ding@xjtlu.edu.cn

Abstract

Five stable clusters sharing the cuboidal [Ni₄O₄] skeleton are subjected to third-order nonlinear optical (NLO) property measurements. Preliminary results suggest that the NLO property is largely defined by the cluster core skeleton and the directly coordinated atoms, with limited contribution from the heavy atoms peripherally attached to the aromatic ligands.

This article is part of the themed collection: Dalton Transactions Inorganic Symposia

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Article information

DOI: https://doi.org/10.1039/C8DT02080A
Article type: Communication
Submitted: 22 May 2018
Accepted: 05 Jun 2018
First published: 05 Jun 2018

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Dalton Trans., 2018,47, 8865-8869

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Evaluating the component contribution to nonlinear optical performances using stable [Ni₄O₄] cuboidal clusters as models

Z. Hao, M. Chao, Y. Liu, Y. Song, J. Yang, L. Ding, W. Zhang and J. Lang, Dalton Trans., 2018, 47, 8865 DOI: 10.1039/C8DT02080A

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