Issue 32, 2018

K11RbB28O48: a new triple-layered borate with an unprecedented [B28O57] fundamental building block

Abstract

A new mixed-alkali borate, K11RbB28O48, has been obtained using the high-temperature solution method. It features a new [B28O57] fundamental building block. Meanwhile, these units further polymerize to form unusual triple-layered anionic groups. Thermal analysis, optical property measurement, and theoretical calculations were performed.

Graphical abstract: K11RbB28O48: a new triple-layered borate with an unprecedented [B28O57] fundamental building block

Supplementary files

Article information

Article type
Communication
Submitted
23 May 2018
Accepted
29 Jun 2018
First published
30 Jun 2018

Dalton Trans., 2018,47, 10833-10836

K11RbB28O48: a new triple-layered borate with an unprecedented [B28O57] fundamental building block

D. Jiang, Y. Wang, B. Zhang, G. Han, Z. Yang and S. Pan, Dalton Trans., 2018, 47, 10833 DOI: 10.1039/C8DT02095G

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