Issue 33, 2018
From the journal:

Dalton Transactions

Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands†

Yoshiya Sekiguchi,a   Fanqiang Meng,a   Hiromasa Tanaka,b   Aya Eizawa, ORCID logo a   Kazuya Arashiba,a   Kazunari Nakajima, ORCID logo a   Kazunari Yoshizawa*b  and  Yoshiaki Nishibayashi ORCID logo *a  

* Corresponding authors

a Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

b Institute for Materials Chemistry and Engineering, Kyushu University, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

Dinitrogen-bridged dititanium and dizirconium complexes bearing anionic pyrrole-based PNP-type pincer ligands are prepared and characterized by X-ray analysis. Their catalytic activity is investigated toward reduction of nitrogen gas into ammonia and hydrazine under mild reaction conditions.

Graphical abstract: Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands

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Article information

DOI
https://doi.org/10.1039/C8DT02739K
Article type
Communication
Submitted
05 Jul 2018
Accepted
24 Jul 2018
First published
25 Jul 2018

Dalton Trans., 2018,47, 11322-11326

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Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands

Y. Sekiguchi, F. Meng, H. Tanaka, A. Eizawa, K. Arashiba, K. Nakajima, K. Yoshizawa and Y. Nishibayashi, Dalton Trans., 2018, 47, 11322 DOI: 10.1039/C8DT02739K

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