Issue 2, 2018
From the journal:

Organic & Biomolecular Chemistry

Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(iii) triflate†

Amandine Xolin,a   Romain Losa,a   Aicha Kaid,a   Cédric Tresse,a   Jean-Marie Beau, ORCID logo ab   François-Didier Boyer ORCID logo *ac  and  Stéphanie Norsikian ORCID logo *a  

* Corresponding authors

a Institut de Chimie des Substances Naturelles, CNRS UPR2301, Univ. Paris-Sud, Université Paris-Saclay, 1 av. de la Terrasse, F-91198 Gif-sur-Yvette, France
E-mail: stephanie.norsikian@cnrs.fr, francois-didier.boyer@cnrs.fr
Web: http://www.icsn.cnrs-gif.fr

b Laboratoire de Synthèse de Biomolécules, Institut de Chimie Moléculaire et des Matériaux d'Orsay, Univ. Paris-Sud, CNRS, Université Paris-Saclay, F-91405 Orsay, France

c Institut Jean-Pierre Bourgin, INRA, AgroParisTech, CNRS, Université Paris-Saclay, RD10, F-78026 Versailles, France
E-mail: francois.boyer@inra.fr

Abstract

The activation of aryl glycosyl sulfone donors has been achieved using scandium(III) triflate and has led to the selective preparation of α-mannosides resulting from a post-glycosylation anomerization.

Graphical abstract: Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(iii) triflate

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Article information

DOI
https://doi.org/10.1039/C7OB02792C
Article type
Paper
Submitted
14 Nov 2017
Accepted
12 Dec 2017
First published
12 Dec 2017

Org. Biomol. Chem., 2018,16, 325-335

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Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(III) triflate

A. Xolin, R. Losa, A. Kaid, C. Tresse, J. Beau, F. Boyer and S. Norsikian, Org. Biomol. Chem., 2018, 16, 325 DOI: 10.1039/C7OB02792C

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