The stereochemical revision of two recently reported rhamnofolane diterpenes, curcusones I and J, was enabled by quantum calculations of NMR shifts and coupling constants at DFT levels. DP4+ results and reexamination of the NMR data suggest that curcusones I and J should be revised as CS32 and CS28, respectively.
A. M. Sarotti, Org. Biomol. Chem., 2018, 16, 944 DOI: 10.1039/C7OB02916K
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