Issue 3, 2018
From the journal:

Inorganic Chemistry Frontiers

Two isomorphous azide/formate Mn(ii) coordination polymers show spin-canted antiferromagnetism only in the formate system†

Jiao-Yang Wang,a   Qian Yang,*b   Yi-Quan Zhang,*c   Guang-Bo Che, ORCID logo d   Jiong-Peng Zhao ORCID logo *a  and  Fu-Chen Liu ORCID logo *ad  

* Corresponding authors

a School of Chemistry and Chemical Engineering, TKL of Organic Solar Cells and Photochemical Conversion, Tianjin University of Technology, Tianjin, 300384 China
E-mail: horryzhao@yahoo.com, fuchenliutj@yahoo.com

b School of Science, Tianjin University of Science & Technology, Tianjin, China
E-mail: qyang1984@tust.edu.cn

c Jiangsu Key Laboratory for NSLSCS, School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, P. R. China
E-mail: zhangyiquan@njnu.edu.cn

d Key Laboratory of Preparation of Environmental Friendly, Jilin Normal University, Ministry of Education, Changchun, China

Abstract

Two isostructural 3D complexes [Mn(L)(N3)·MeOH]n (1) and [Mn(L)(HCO2)·MeOH]n (2) (HL = pyrazine-2-carboxylic acid) were synthesized by using a solvothermal method. Magnetic studies indicate that 1 was a strong antiferromagnet, whereas 2 was a weak antiferromagnet with TN 38.5 K.

Graphical abstract: Two isomorphous azide/formate Mn(ii) coordination polymers show spin-canted antiferromagnetism only in the formate system

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Article information

DOI
https://doi.org/10.1039/C7QI00789B
Article type
Research Article
Submitted
13 Dec 2017
Accepted
19 Jan 2018
First published
19 Jan 2018

Inorg. Chem. Front., 2018,5, 719-722

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Two isomorphous azide/formate Mn(II) coordination polymers show spin-canted antiferromagnetism only in the formate system

J. Wang, Q. Yang, Y. Zhang, G. Che, J. Zhao and F. Liu, Inorg. Chem. Front., 2018, 5, 719 DOI: 10.1039/C7QI00789B

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