Issue 4, 2018
From the journal:

Inorganic Chemistry Frontiers

Chiral bis(phthalocyaninato) terbium double-decker compounds with enhanced single-ion magnetic behavior†

Kang Wang,a   Fang Ma,b   Dongdong Qi,a   Xin Chen,a   Yuxiang Chen,a   Yan-Cong Chen, ORCID logo c   Hao-Ling Sun, ORCID logo *b   Ming-Liang Tong ORCID logo *c  and  Jianzhuang Jiang ORCID logo *a  

* Corresponding authors

a Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China
E-mail: jianzhuang@ustb.edu.cn

b Department of Chemistry and Beijing Key Laboratory of Energy Conversion and Storage Materials, Beijing Normal University, Beijing 100875, China
E-mail: haolingsun@bnu.edu.cn

c Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P. R. China
E-mail: tongml@mail.sysu.edu.cn

Abstract

Chiral binaphthyl substituents were incorporated onto the phthalocyanine periphery in both homoleptic and heteroleptic bis(phthalocyaninato) terbium single-ion magnets, which exhibit blocking temperatures as high as 15 K and 28 K, respectively, providing an alternative method towards enhancing the magnetic behavior.

Graphical abstract: Chiral bis(phthalocyaninato) terbium double-decker compounds with enhanced single-ion magnetic behavior

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Article information

DOI
https://doi.org/10.1039/C8QI00066B
Article type
Research Article
Submitted
25 Jan 2018
Accepted
22 Feb 2018
First published
23 Feb 2018

Inorg. Chem. Front., 2018,5, 939-943

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Chiral bis(phthalocyaninato) terbium double-decker compounds with enhanced single-ion magnetic behavior

K. Wang, F. Ma, D. Qi, X. Chen, Y. Chen, Y. Chen, H. Sun, M. Tong and J. Jiang, Inorg. Chem. Front., 2018, 5, 939 DOI: 10.1039/C8QI00066B

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