Robust heterometallic MOF catalysts for the cyanosilylation of aldehydes†
Xiao-Ping
Zhou 
*a
and
Dan
Li
*a
*a
and
Dan
Li
*a
Abstract
In this work, Zn2+ and Cu2+ ions are doped into a Mn2+ based frail MOF (STU-2) to form heterometallic MOFs. These metal doped MOFs show a good stability and heterogeneous catalytic activity for the cyanosilylation reactions of aromatic aldehydes. The catalysts can be reused at least for three cycles.
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