Rhodium-catalyzed intramolecular carbosilylation of alkynes via C(sp3)–Si bond cleavage

Qi Yang; Liang Liu; Yue Chi; Wei Hao; Wen-Xiong Zhang; Zhenfeng Xi

doi:10.1039/C7QO00927E

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Rhodium-catalyzed intramolecular carbosilylation of alkynes via C(sp³)–Si bond cleavage†

Qi Yang,^a Liang Liu,^a Yue Chi,^a Wei Hao,^a Wen-Xiong Zhang

*^a and Zhenfeng Xi

*^ab

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
E-mail: zfxi@pku.edu.cn

^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 200032, China

Abstract

A Rh(I)-catalyzed intramolecular cis-carbosilylation of alkynes was achieved. The cleavage of an alkyl–Si bond in a trimethylsilyl group of 8-alkynyl naphthalene derivatives was followed by cis-addition to the alkynyl moiety, affording silatricyclic compounds in good yields.

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Article information

DOI: https://doi.org/10.1039/C7QO00927E
Article type: Research Article
Submitted: 11 Oct 2017
Accepted: 02 Dec 2017
First published: 04 Dec 2017

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Org. Chem. Front., 2018,5, 860-863

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Rhodium-catalyzed intramolecular carbosilylation of alkynes via C(sp³)–Si bond cleavage

Q. Yang, L. Liu, Y. Chi, W. Hao, W. Zhang and Z. Xi, Org. Chem. Front., 2018, 5, 860 DOI: 10.1039/C7QO00927E

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