Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines

Linfeng Cui; Yang'en You; Xueling Mi; Sanzhong Luo

doi:10.1039/C8QO00496J

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Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines†

Linfeng Cui,^a Yang'en You,^b Xueling Mi

*^a and Sanzhong Luo

*^b

Author affiliations

* Corresponding authors

^a College of Chemistry, Beijing Normal University, Xinjiekouwai Street 19, Beijing 100875, China
E-mail: xlmi@bnu.edu.cn

^b Key Laboratory for Molecular Recognition and Function, Institute of Chemistry, the Chinese Academy of Sciences, Beijing 100190, China
E-mail: luosz@iccas.ac.cn

Abstract

A simple chiral primary amine catalyst was identified to enable effective catalysis in direct α-sulfenylation of acyclic and cyclic β-ketocarbonyls with good yields and excellent enantioselectivities.

This article is part of the themed collection: Organic Chemistry Frontiers HOT articles for 2018

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Article information

DOI: https://doi.org/10.1039/C8QO00496J
Article type: Research Article
Submitted: 18 May 2018
Accepted: 14 Jun 2018
First published: 15 Jun 2018

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Org. Chem. Front., 2018,5, 2313-2316

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Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines

L. Cui, Y. You, X. Mi and S. Luo, Org. Chem. Front., 2018, 5, 2313 DOI: 10.1039/C8QO00496J

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Organic Chemistry Frontiers

Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines†

Abstract

Supplementary files

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Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines

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