Low efficiency roll-off and high color stability pure fluorescent white organic light-emitting diode based exciplex host

Abstract

Pure fluorescent WOLEDs with low efficiency roll-off and high color stability were realized by employing an exciplex host. Due to incomplete energy transfer from the blue exciplex host of mCP : PO-T2T to the orange fluorescent dopant of rubrene, the WOLEDs showed a maximum current efficiency, power efficiency and EQE of 14.2 cd A⁻¹, 12.8 lm W⁻¹ and 4.90%, respectively. To our surprise, a rather small roll-off ratio of 8.2% from the maximum EQE to the EQE at 1000 cd m⁻² and stable white light-emitting spectra with CIE coordinates of (0.384 ± 0.001, 0.439 ± 0.002) from 4 V to 8 V were obtained simultaneously. The bipolarity and triplet exciton up-conversion of the exciplex host played key roles in delivering excellent performance. More detailed discussions are also provided.