Liquid crystallinity of carbon nanotubes

Abstract

In this review, we first briefly recapitulate the orientation characteristics of liquid crystalline carbon nanotubes (CNTs), emphasizing their inherent properties. Both the high Young's modulus and the strong attractive interaction between them make the liquid crystallinity apt to show splay deformations (splay defects). It is these defects that often produce apparent low-order structures for long and deformed nanotubes. However, the application of doping, shearing, magnetic or electric fields will be efficient routes toward highly ordered CNT assemblies from such defects. Then, we describe the electrical behavior of CNTs in the electric field, which combines desirable features of the CNTS with those of classical liquid crystals (LCs). An electric field will generate an induced dipole moment on CNTs and align them in the field direction, minimizing the dipolar energy. Finally, we review the potential application of CNTs in the area of liquid crystal displays (LCD). In the LC cell unit, CNTs as dopants in LC layers can have compatible stability with LCs, with the orientation consistent and with surprising complementary advantages. And also CNT films as nanostructured electrodes can substitute ITO electrodes in the LC cell unit, exhibiting a strong electrical anisotropy due to their excellent axial conductivity. Furthermore, CNT films as an alignment layer have the potential to replace the traditional PI film, aligning LC molecules effectively along the direction of the nanotubes. Besides, CNTs acting as polarizers can absorb or transmit incident light when the electric vector propagates parallel or perpendicular to the nanotube axis. All of these applications demonstrate that CNTs in LC ordering will effectively improve the performance of materials and their related devices. Thus, we should improve the ordering of CNT assemblies as far as possible, which is critical to make full use of their exceptional axial properties and further to develop novel materials and applications successfully.