Sm2O3/Co3O4 catalysts prepared by dealloying for low-temperature CO oxidation

Abstract

A series of Co₃O₄ catalysts modified by Sm were prepared by a combined dealloying and calcination approach, and the catalytic activities were evaluated using CO catalytic oxidation. The Sm₂O₃/Co₃O₄ catalysts were composed of a large number of nanorods and nanosheets, and exhibited a three-dimensional supporting structure with pores. The experimental results revealed that the addition of a small amount of Sm into the precursor AlCo alloy led to a dealloyed sample with improved catalytic activity, and the dealloyed Al₉₀Co_9.5Sm_0.5 ribbons (0.5 Sm₂O₃/Co₃O₄) calcined at 300 °C showed the highest activity for CO oxidation with complete CO conversion at 135 °C, moreover, CO conversion almost no attenuation, even after 70 hours of catalytic oxidation, which is superior to that of Co₃O₄. The enhanced catalytic activity of the Sm₂O₃/Co₃O₄ catalyst can be attributed to the large specific surface area, more reactive oxygen species and Co³⁺ ion, as well as electronic interactions between Sm and Co.