Ionic-liquid-assisted one-pot synthesis of Cu2O nanoparticles/multi-walled carbon nanotube nanocomposite for high-performance asymmetric supercapacitors

Abstract

Finding earth-abundant and high-performance electrode materials for supercapacitors is a demanding challenge in the energy storage field. Cuprous oxide (Cu₂O) has attracted increasing attention due to its theoretically high specific capacitance, however, the development of Cu₂O-based electrodes with superior capacitive performance is still challenging. We herein report a simple and effective ionic-liquid-assisted sputtering approach to synthesizing the Cu₂O nanoparticles/multi-walled carbon nanotubes (Cu₂O/MWCNTs) nanocomposite for high-performance asymmetric supercapacitors. The Cu₂O/MWCNTs nanocomposite delivers a high specific capacitance of 357 F g⁻¹, good rate capability and excellent capacitance retention of about 89% after 20 000 cycles at a current density of 10 A g⁻¹. The high performance is attributed to the uniform dispersion of small-sized Cu₂O nanoparticles on conductive MWCNTs, which offers plenty of redox active sites and thus improve the electron transfer efficiency. Oxygen vacancies are further introduced into Cu₂O by the NaBH₄ treatment, providing the oxygen-deficient Cu₂O/MWCNTs (r-Cu₂O/MWCNTs) nanocomposite with significantly improved specific capacitance (790 F g⁻¹) and cycling stability (∼93% after 20 000 cycles). The assembled asymmetric supercapacitor based on the r-Cu₂O/MWCNTs//activated carbon (AC) structure achieves a high energy density of 64.2 W h kg⁻¹ at 825.3 W kg⁻¹, and long cycling life. This work may form a foundation for the development of both high capacity and high energy density supercapacitors by showcasing the great potential of earth-abundant Cu-based electrode materials.