Issue 31, 2018, Issue in Progress
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RSC Advances

A weaker donor shows higher oxidation state upon aggregation†

Longfei Ma,a   Haili Peng,a   Xiaofeng Lu,a   Lei Liua  and  Xiangfeng Shao ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Tianshui Southern Road 222, Lanzhou, Gansu Province, P. R. China
E-mail: shaoxf@lzu.edu.cn
Fax: +86 0931 8915557
Tel: +86 0931 8912500

Abstract

The charge-transfer between TTFs and I2 shows that the stronger donor TTF1 is in a cation radical state and the weaker donor TTF2 is neutral in solution, whereas TTF1 exists as a cation radical and TTF2 is dicationic in complexes. The dicationic and neutral states of TTF2 are reversible upon aggregation and solvation.

Graphical abstract: A weaker donor shows higher oxidation state upon aggregation

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Article information

DOI
https://doi.org/10.1039/C8RA02956C
Article type
Paper
Submitted
06 Apr 2018
Accepted
04 May 2018
First published
11 May 2018
This article is Open Access
Creative Commons BY license

RSC Adv., 2018,8, 17321-17324

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A weaker donor shows higher oxidation state upon aggregation

L. Ma, H. Peng, X. Lu, L. Liu and X. Shao, RSC Adv., 2018, 8, 17321 DOI: 10.1039/C8RA02956C

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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