Co9S8 nanoparticle-decorated carbon nanofibers as high-performance supercapacitor electrodes

Abstract

This work reported Co₉S₈ nanoparticle-decorated carbon nanofibers (CNF) as a supercapacitor electrode. By using a mild ion-exchange method, the cobalt oxide-based precursor nanoparticles were transformed to Co₉S₈ nanoparticles in a microwave hydrothermal process, and these nanoparticles were decorated onto a carbon nanofiber backbone. The composition of the nanofibers can be readily tuned by varying the Co acetate content in the precursor. The porous carbon nanofibers offered a fast electron transfer pathway while the well dispersed Co₉S₈ nanoparticles acted as the redox center for energy storage. As a result, high specific capacitance of 718 F g⁻¹ at 1 A g⁻¹ can be achieved with optimized Co₉S₈ loading. The assembled asymmetric supercapacitor with Co₉S₈/CNF as the cathode showed a high energy density of 23.8 W h kg⁻¹ at a power density of 0.75 kW kg⁻¹ and good cycling stability (16.9% loss over 10 000 cycles).