Anisotropic growth of gas–liquid precipitated ceria mesocrystals to wires several micrometers in length

Abstract

Ceria (CeO₂) wires with lengths of 6 μm and diameters of tens of nanometers are fabricated through the anisotropic growth of mesocrystals. In the gas–liquid precipitation process, an aqueous Ce(NO₃)₃ solution is used as a starting material and NH₃ gas is used to induce CeO₂ precipitation at the gas–liquid interface. CeO₂ mesocrystals, formed by this process at 60 °C, grow in the direction of 〈011〉 into micrometer length wires exposing {001} and {011} on their side walls. It is shown that the initial pH of the starting material solution is a key parameter to attain anisotropic growth of the CeO₂ mesocrystals. We thus propose the formation mechanism of micrometer length-CeO₂ wires from mesocrystals.