Adsorption–desorption of CO2 on zeolite-Y-templated carbon at various temperatures†
Abstract
This study aims to investigate the adsorption–desorption of CO2 on a micro-mesoporous zeolite-Y-templated carbon (ZTC) at various temperatures. ZTC was synthesized via sucrose impregnation, carbonization, and template removal. The adsorption–desorption of CO2 on ZTC was performed using the gravimetric method. Results showed that the CO2 adsorption capacity was 9.51 wt%, 5.60 wt%, and 3.47 wt%, and desorbed up to 59.83%, 69.70%, 77.5% for temperatures of 30 °C, 40 °C, and 50 °C, respectively. The adsorption process of CO2 at temperatures of 30 °C and 40 °C follow the pseudo-second order, while at 50 °C follows intra-particle diffusion. The thermodynamic analyses indicate that the adsorption was due to physisorption.