Kinetically controlled redox behaviors of K0.3MnO2 electrodes for high performance sodium-ion batteries

Abstract

Due to its abundance, high theoretical capacity, and environmental compatibility, manganese dioxide (MnO₂) is regarded as a potential electrode material for sodium-ion batteries. Nevertheless, severe side reactions including manganese dissolution and the Mn³⁺ disproportionation reaction are common challenges to manganese-based electrodes that cause a huge capacity fading, further limiting their practical applications. To address these issues, here the environmentally friendly K-birnessite MnO₂ (K_0.3MnO₂) nanosheets are directly inkjet-printed on the stainless steel sheet to serve as the electrode, while a diglyme-based electrolyte is used to fabricate a sodium-ion battery. In contrast to the conventional two-step redox reactions involving Mn⁴⁺/Mn³⁺/Mn²⁺ couples, the as-printed K_0.3MnO₂ electrode shows an enhanced redox activity of the Mn⁴⁺/Mn³⁺ couple, along with a suppressed redox activity of the Mn³⁺/Mn²⁺ couple that restricts the side reactions. The active particle size, electrode structure and electrolyte conditions could be identified as the key factors that contribute to the performance optimization. The electrode simultaneously and unprecedentedly achieves a working voltage of 2.5 V, maximum energy and power densities of 587 W h kg_cathode⁻¹ and 75 kW kg_cathode⁻¹, respectively, with 99.5% capacity retention for 500 cycles at 1 A g⁻¹.