Issue 5, 2019

A mono-metallic Pd(ii)-cage featuring two different polar binding sites

Abstract

The tetra-α isomer of a super aryl-extended tetra-pyridyl calix[4]pyrrole self-assembles into a mono-metallic Pd(II)-cage featuring two different and converging polar binding sites. Mono- and di-topic polar guests are bound reversibly in the cage. A mechanism for guest exchange in the cage complexes is proposed.

Graphical abstract: A mono-metallic Pd(ii)-cage featuring two different polar binding sites

Supplementary files

Article information

Article type
Communication
Submitted
19 Nov 2018
Accepted
11 Dec 2018
First published
12 Dec 2018

Chem. Commun., 2019,55, 604-607

A mono-metallic Pd(II)-cage featuring two different polar binding sites

L. Escobar, D. Villarón, E. C. Escudero-Adán and P. Ballester, Chem. Commun., 2019, 55, 604 DOI: 10.1039/C8CC09195A

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