A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

Akira Nagai; Takashi Nakamura; Tatsuya Nabeshima

doi:10.1039/C8CC09643K

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A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands†

Akira Nagai,^a Takashi Nakamura

^a and Tatsuya Nabeshima

*^a

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* Corresponding authors

^a Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS), University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan
E-mail: nabesima@chem.tsukuba.ac.jp

Abstract

A macrocyclic hexanuclear palladium complex, which accumulates coordination sites on metals inside the cavity, was synthesized. The macrocycle was found to take a uniquely-twisted C₂-symmetric conformation when six molecules of a bulky pyridine derivative coordinated to the palladium.

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DOI: https://doi.org/10.1039/C8CC09643K
Article type: Communication
Submitted: 04 Dec 2018
Accepted: 08 Jan 2019
First published: 09 Jan 2019

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Chem. Commun., 2019,55, 2421-2424

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A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

A. Nagai, T. Nakamura and T. Nabeshima, Chem. Commun., 2019, 55, 2421 DOI: 10.1039/C8CC09643K

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Chemical Communications

A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands†

Abstract

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A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

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