Issue 23, 2019
From the journal:

Chemical Communications

Room temperature hysteretic spin crossover in a new cyanoheterometallic framework†

Volodymyr M. Hiiuk,abc   Sergiu Shova, ORCID logo d   Aurelian Rotaru,e   Vadim Ksenofontov,f   Igor O. Fritsky ORCID logo ab  and  Il'ya A. Gural'skiy ORCID logo *ab  

* Corresponding authors

a Department of Chemistry, Taras Shevchenko National University of Kyiv, 64 Volodymyrska St., 01601 Kyiv, Ukraine
E-mail: illia.guralskyi@univ.kiev.ua

b UkrOrgSyntez Ltd., 67 Chervonotkatska St., 02094 Kyiv, Ukraine

c Faculty of Natural Sciences, National University of Kyiv-Mohyla Academy, 2 Skovorody St., 04070 Kyiv, Ukraine

d “Petru Poni” Institute of Macromolecular Chemistry, 41A Aleea Gr. Ghica Voda, 700487 Iasi, Romania

e Faculty of Electrical Engineering and Computer Science & Research Center MANSiD, Stefan cel Mare University, 13 Universitatii St., 720229 Suceava, Romania

f Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg University of Mainz, Duesbergweg 10–14, Mainz 55099, Germany

Abstract

A new iron(II)-based spin-crossover compound with thermal hysteresis operating under ambient conditions is reported. This complex exhibits a high reproducibility of the spin transition in many successive thermal cycles, stability of both spin states at room temperature and an attractive operational temperature range.

Graphical abstract: Room temperature hysteretic spin crossover in a new cyanoheterometallic framework

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8CC10260K
Article type
Communication
Submitted
28 Dec 2018
Accepted
15 Feb 2019
First published
19 Feb 2019

Chem. Commun., 2019,55, 3359-3362

Permissions

Request permissions

Room temperature hysteretic spin crossover in a new cyanoheterometallic framework

V. M. Hiiuk, S. Shova, A. Rotaru, V. Ksenofontov, I. O. Fritsky and I. A. Gural'skiy, Chem. Commun., 2019, 55, 3359 DOI: 10.1039/C8CC10260K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements