Issue 25, 2019
From the journal:

Chemical Communications

A disk-type polyarene containing four B←N units†

Yang Min,ab   Chuandong Dou,*a   Hongkun Tian,a   Jun Liu ORCID logo *a  and  Lixiang Wang ORCID logo a  

* Corresponding authors

a State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, People's Republic of China
E-mail: chuandong.dou@ciac.ac.cn, liujun@ciac.ac.cn

b University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China

Abstract

In this manuscript, we report a disk-type polyarene consisting of an all-hexagon π-framework and four B←N units. It exhibits intriguing electronic structures and opto-electronic properties, such as locally modulated (anti)aromaticity, strong red fluorescence and n-type semiconductor characteristics, thus representing a new kind of π-molecule containing B←N units.

Graphical abstract: A disk-type polyarene containing four B←N units

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Article information

DOI
https://doi.org/10.1039/C9CC00769E
Article type
Communication
Submitted
28 Jan 2019
Accepted
28 Feb 2019
First published
01 Mar 2019

Chem. Commun., 2019,55, 3638-3641

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A disk-type polyarene containing four B←N units

Y. Min, C. Dou, H. Tian, J. Liu and L. Wang, Chem. Commun., 2019, 55, 3638 DOI: 10.1039/C9CC00769E

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