Issue 26, 2019

Visible-light-induced Pd-catalyzed ortho-trifluoromethylation of acetanilides with CF3SO2Na under ambient conditions in the absence of an external photocatalyst

Abstract

A visible-light-induced Pd-catalyzed ortho-trifluoromethylation of acetanilides with CF3SO2Na was developed. The reaction proceeded smoothly at room temperature in air without any external photocatalyst or additive, providing the desired products in moderate to good yields with good functional group tolerance and regioselectivity.

Graphical abstract: Visible-light-induced Pd-catalyzed ortho-trifluoromethylation of acetanilides with CF3SO2Na under ambient conditions in the absence of an external photocatalyst

Supplementary files

Article information

Article type
Communication
Submitted
03 Feb 2019
Accepted
05 Mar 2019
First published
06 Mar 2019

Chem. Commun., 2019,55, 3737-3740

Visible-light-induced Pd-catalyzed ortho-trifluoromethylation of acetanilides with CF3SO2Na under ambient conditions in the absence of an external photocatalyst

L. Zou, P. Li, B. Wang and L. Wang, Chem. Commun., 2019, 55, 3737 DOI: 10.1039/C9CC01014A

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