Rapid screening of the hydrogen bonding strength of radicals by electrochemiluminescent probes

Abstract

In this study, we discovered that a clear decrease in the electrochemiluminescence (ECL) intensities of luminol occurred upon increasing the electron donating capacity of amides. Therefore, herein, a novel ECL probe was used for the first time to screen the strength of the hydrogen bonds formed between HOO˙ radicals and amides. This proposed hydrogen bonding strength-sensitive ECL probe has a significant prospect in distinguishing the hydrogen bonding strength of different radicals.