2D MOF induced accessible and exclusive Co single sites for an efficient O-silylation of alcohols with silanes

Xin Wang; Peng Li; Zhijun Li; Wenxing Chen; Huang Zhou; Yafei Zhao; Xiaoqian Wang; Lirong Zheng; Juncai Dong; Yue Lin; Xusheng Zheng; Wensheng Yan; Jian Yang; Zhengkun Yang; Yunteng Qu; Tongwei Yuan; Yuen Wu; Yadong Li

doi:10.1039/C9CC01717H

2D MOF induced accessible and exclusive Co single sites for an efficient O-silylation of alcohols with silanes†

Xin Wang,^a Peng Li,^a Zhijun Li,^a Wenxing Chen,^b Huang Zhou,^a Yafei Zhao,^a Xiaoqian Wang,

^a Lirong Zheng,

^c Juncai Dong,^c Yue Lin,

^a Xusheng Zheng,^d Wensheng Yan,^d Jian Yang,^a Zhengkun Yang,^a Yunteng Qu,^a Tongwei Yuan,^a Yuen Wu

*^a and Yadong Li

*^b

Author affiliations

* Corresponding authors

^a Department of Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), University of Science and Technology of China, Hefei 230026, China
E-mail: yuenwu@ustc.edu.cn

^b Department of Chemistry, Tsinghua University, Beijing 100084, China

^c Institute of High Energy Physics, Beijing 100029, China

^d National Synchrotron Radiation Laboratory (NSRL), University of Science and Technology of China, Hefei, Anhui 230029, China

Abstract

Co single atoms anchored on ultrathin two-dimensional nitrogen-doped carbon (Co SAs/2D N–C) were in situ derived from 2D metal–organic frameworks (MOFs). These ultrathin nanosheets functionalized by the isolated Co atoms possess a high density of active sites and accessible surfaces, exhibiting an exceptional catalytic performance in the oxidation of silanes.

Chemical Communications

2D MOF induced accessible and exclusive Co single sites for an efficient O-silylation of alcohols with silanes†

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2D MOF induced accessible and exclusive Co single sites for an efficient O-silylation of alcohols with silanes

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