Issue 51, 2019
From the journal:

Chemical Communications

Construction of polycyclic bridged indene derivatives by a tandem 1,3-rearrangement/intramolecular Friedel–Crafts cyclization of propargyl acetates†

Jiantao Zhang,a   Zhehui Liao,a   Lianfen Chen, ORCID logo a   Huanfeng Jiang ORCID logo a  and  Shifa Zhu ORCID logo *ab  

* Corresponding authors

a Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, P. R. China
E-mail: zhusf@scut.edu.cn

b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, P. R. China

Abstract

An unprecedented Lewis acid-catalyzed cascade 1,3-rearrangement/Friedel–Crafts cyclization of propargyl acetates is developed for the construction of polycyclic bridged indene derivatives in moderate to good yields. This practical procedure features mild conditions, broad substrate scope, and easy operation.

Graphical abstract: Construction of polycyclic bridged indene derivatives by a tandem 1,3-rearrangement/intramolecular Friedel–Crafts cyclization of propargyl acetates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9CC03715B
Article type
Communication
Submitted
15 May 2019
Accepted
30 May 2019
First published
30 May 2019

Chem. Commun., 2019,55, 7382-7385

Permissions

Request permissions

Construction of polycyclic bridged indene derivatives by a tandem 1,3-rearrangement/intramolecular Friedel–Crafts cyclization of propargyl acetates

J. Zhang, Z. Liao, L. Chen, H. Jiang and S. Zhu, Chem. Commun., 2019, 55, 7382 DOI: 10.1039/C9CC03715B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements