Issue 54, 2019
From the journal:

Chemical Communications

2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant†

Mekhman S. Yusubov,*a   Natalia S. Soldatova,a   Pavel S. Postnikov,a   Rashid R. Valiev,ab   Akira Yoshimura, ORCID logo ac   Thomas Wirth, ORCID logo d   Victor N. Nemykine  and  Viktor V. Zhdankin*c  

* Corresponding authors

a The Tomsk Polytechnic University, 634050 Tomsk, Russia
E-mail: yusubov@mail.ru

b Tomsk State University, 634050 Tomsk, Russia

c Department of Chemistry and Biochemistry, University of Minnesota, Duluth, MN 55812, USA
E-mail: vzhdanki@d.umn.edu

d School of Chemistry, Cardiff University, Park Place, Cardiff, UK

e Department of Chemistry, University of Manitoba, Winnipeg, MB R3T 2N2, Canada

Abstract

A ditriflate derivative of 2-iodoxybenzoic acid (IBX) was prepared by the reaction of IBX with trifluoromethanesulfonic acid and characterized by single crystal X-ray crystallography. IBX-ditriflate is the most powerful oxidant in a series of structurally similar IBX derivatives which is best illustrated by its ability to readily oxidize hydrocarbons and the oxidation resistant polyfluoroalcohols.

Graphical abstract: 2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant

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Article information

DOI
https://doi.org/10.1039/C9CC04203B
Article type
Communication
Submitted
31 May 2019
Accepted
07 Jun 2019
First published
07 Jun 2019

Chem. Commun., 2019,55, 7760-7763

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2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(V) oxidant

M. S. Yusubov, N. S. Soldatova, P. S. Postnikov, R. R. Valiev, A. Yoshimura, T. Wirth, V. N. Nemykin and V. V. Zhdankin, Chem. Commun., 2019, 55, 7760 DOI: 10.1039/C9CC04203B

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