Issue 71, 2019
From the journal:

Chemical Communications

NO sorption, in-crystal nitrite and nitrate production with arylamine oxidation in gas–solid single crystal to single crystal reactions†

Mads Sondrup Møller, ORCID logo a   Alexander Haag, ORCID logo a   Vickie McKee ORCID logo a  and  Christine J. McKenzie ORCID logo *a  

* Corresponding authors

a Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, 5230 Odense M, Denmark
E-mail: mckenzie@sdu.dk

Abstract

A bridging nitrite and a nitrate counter anion per Co2 site are generated in-crystal and an arylamine group on the ligand scaffold is oxidised to a nitro group when nitric oxide (NO) is chemisorbed by molecular crystals of cobalt complexes.

Graphical abstract: NO sorption, in-crystal nitrite and nitrate production with arylamine oxidation in gas–solid single crystal to single crystal reactions

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Article information

DOI
https://doi.org/10.1039/C9CC05315H
Article type
Communication
Submitted
10 Jul 2019
Accepted
05 Aug 2019
First published
15 Aug 2019

Chem. Commun., 2019,55, 10551-10554

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NO sorption, in-crystal nitrite and nitrate production with arylamine oxidation in gas–solid single crystal to single crystal reactions

M. S. Møller, A. Haag, V. McKee and C. J. McKenzie, Chem. Commun., 2019, 55, 10551 DOI: 10.1039/C9CC05315H

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