The toxic halogenated anilines 2,4,6-tribromoaniline, 2,4,6-trichloroaniline and their dibromochloro and bromodichloro derivatives were considered as compounds of exclusive synthetic origin. Labeling studies and kinetic experiments confirmed that these substances are also biosynthesized by a marine biofilm forming microalga. They represent a novel class of halogenated natural products.
T. U. H. Baumeister, M. Staudinger, M. Wirgenings and G. Pohnert, Chem. Commun., 2019, 55, 11948 DOI: 10.1039/C9CC05992J
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