Single-size platinum Pt6 subnanoclusters exhibit superior mass-specific and surface-specific activities for the oxygen reduction reaction. The enhanced activity is attributed to polarized electron distributions based on rigorous structure characterization by X-ray absorption fine structure spectroscopy and density functional theory.
H. Tsunoyama, A. Ohnuma, K. Takahashi, A. Velloth, M. Ehara, N. Ichikuni, M. Tabuchi and A. Nakajima, Chem. Commun., 2019, 55, 12603 DOI: 10.1039/C9CC06327G
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