Issue 80, 2019
From the journal:

Chemical Communications

Chemically grafting nanoscale UIO-66 onto polypyrrole nanotubes for long-life lithium–sulfur batteries†

Qi Li, ORCID logo *a   Hai Zhu,b   Yanfeng Tang, ORCID logo a   Peng Zhu,a   Haiyan Ma,a   Cunwang Gea  and  Feng Yan ORCID logo *b  

* Corresponding authors

a Department of Polymer Materials and Science, College of Chemistry and Chemical Engineering, Nantong University, Nantong, China
E-mail: zhuiqiuzhizhuo@163.com

b Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, China
E-mail: fyan@suda.edu.cn

Abstract

A versatile strategy for a facile approach to chemical graft MOFs onto polypyrrole nanotubes (PPyNTs@MOFs) is designed and fabricated rationally by means of 1,4-dibromobutane linkage. Various MOFs arranged randomly close-packed on PPyNTs, including Co2+, Cu2+, Zn2+, Mn2+, Fe3+, Al3+, Ti4+, Cr4+, Zr4+ and V4+, have been synthesized successfully. The as-prepared PPyNT@UIO-66 hybrids, used as a cathode carrier, exhibit excellent cyclic stability in Li–S batteries via strong physical and chemical adsorption/affinity with polysulfides.

Graphical abstract: Chemically grafting nanoscale UIO-66 onto polypyrrole nanotubes for long-life lithium–sulfur batteries

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Article information

DOI
https://doi.org/10.1039/C9CC06362E
Article type
Communication
Submitted
16 Aug 2019
Accepted
16 Sep 2019
First published
16 Sep 2019

Chem. Commun., 2019,55, 12108-12111

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Chemically grafting nanoscale UIO-66 onto polypyrrole nanotubes for long-life lithium–sulfur batteries

Q. Li, H. Zhu, Y. Tang, P. Zhu, H. Ma, C. Ge and F. Yan, Chem. Commun., 2019, 55, 12108 DOI: 10.1039/C9CC06362E

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